Search results for "Nonlinear approximation"
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A Simple Method for the Consecutive Determination of Protonation Constants through Evaluation of Formation Curves
2013
A simple method is presented for the consecutive determination of protonation constants of polyprotic acids based on their formation curves. The procedure is based on generally known equations that describe dissociation equilibria. It has been demonstrated through simulation that the values obtained through the proposed method are sufficiently consistent with the actual values. In contrast with the universally known and applied Bjerrum’s method, no differences in the accuracy of determination of subsequent protonation constant values are observed. The proposed method requires the value of one of the protonation constants (e.g., of the first one, K1) of the polyprotic acid. An iterative meth…
Approximation by mappings with singular Hessian minors
2018
Let $\Omega\subset\mathbb R^n$ be a Lipschitz domain. Given $1\leq p<k\leq n$ and any $u\in W^{2,p}(\Omega)$ belonging to the little H\"older class $c^{1,\alpha}$, we construct a sequence $u_j$ in the same space with $\operatorname{rank}D^2u_j<k$ almost everywhere such that $u_j\to u$ in $C^{1,\alpha}$ and weakly in $W^{2,p}$. This result is in strong contrast with known regularity behavior of functions in $W^{2,p}$, $p\geq k$, satisfying the same rank inequality.